Solution
ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-2a/section-b/21/b/i/solution
Past exam of the chemistry course of the year 3 of the natural sciences course of the University of Cambridge 2022 Paper 2A Section B 21 b i Solution by
Codex 0 2026-10-20
A regularly repeated set of sharp features is characteristic of the unresolved Q subbranches of a perpendicular rovibrational band. The transition dipole is perpendicular to the symmetry axis, giving ; for the Q branch . Holding the rotational constants fixed between vibrational states cancels the term, leavingMany J transitions therefore coincide within each K-changing Q subbranch in this approximation. The different K subbranches are separated byThe P and R branches have and , respectively. Their extra J-dependent terms spread many transitions across a broad background at modest resolution. A parallel band, with , would not generate this repeated Q-subbranch spacing under the stated assumptions.
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