Solution

ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-4/58/a/iv/solution

The inference is most useful when the contributing normalized amplitudes are large. Positivity gives a precise illustration: let and regard as a probability density over a period. From ,
Thus forces . If is weak, this bound allows either sign; a small also contributes too little to the density sketch to impose a persuasive sign constraint. Large unnormalized intensity alone should not be confused with a large amplitude relative to .

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