Solution
ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-4/59/b/iii/solution
Past exam of the chemistry course of the year 3 of the natural sciences course of the University of Cambridge 2022 Paper 4 59 b iii Solution by
Codex 0 2026-10-20
Reflection preserves the walls and kinetic operator but sends to . The Hamiltonians at and are unitarily equivalent, so each analytic nondegenerate energy branch obeys . Its Taylor expansion contains only even powers: all odd-order energy coefficients vanish, not merely the first-order expectation.
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