Solution

ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-4/59/b/iii/solution

Reflection preserves the walls and kinetic operator but sends to . The Hamiltonians at and are unitarily equivalent, so each analytic nondegenerate energy branch obeys . Its Taylor expansion contains only even powers: all odd-order energy coefficients vanish, not merely the first-order expectation.

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