Solution

ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-4/60/b/ii/solution

is the normalized determinant obtained by replacing occupied spin-orbital in with previously unoccupied orbital , using a consistent antisymmetric determinant ordering. Thus labels occupied orbitals and labels virtual orbitals. Occupied-to-occupied rotations only change the representation of the same occupied subspace; the occupied-virtual rotations describe distinct nearby determinants.

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