Solution

ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-4/61/d/i/solution

is a dimensionless reduced density gradient. It measures inhomogeneity relative to the local density scale, vanishes for a uniform gas, and allows a generalized gradient approximation correction to distinguish rapidly varying density from slowly varying density with the same local value.
The parameter controls the correction strength in the Becke 1988 exchange functional; it was fitted to atomic exchange energies. The large-gradient denominator simultaneously produces the intended asymptotic behavior, so its role is more constrained than an arbitrary multiplicative adjustment.[ref]

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