Solution

ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-4/61/d/iv/solution

In the usual exchange-hole representation, the hole around an electron integrates to charge deficit . Far outside a finite system, the localized hole therefore looks like a unit opposite charge at distance . The Coulomb interaction has leading scale , and the exchange pair energy carries the usual factor to avoid double counting, giving exchange energy per electron .
This energy-per-electron tail should not be confused with the exchange or exchange-correlation potential, whose leading coefficient is generally in the corresponding exact finite-system setting. Local energy-density representations also require a specified gauge; the question uses the conventional exchange-hole interpretation.

New to topics? Read the docs here!