Solution

ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-4/65/d/i/solution

The reconstruction matrix has area multiplier . A bulk-terminated monatomic surface would therefore contain atoms in that projected cell, whereas the reconstructed top layer contains . Its density increases by
The denser layer can reduce the large tensile surface stress and improve the outermost layer's preferred metallic bonding, at the expense of registry/domain-boundary and elastic costs. Surface atoms need not prefer exactly the same equilibrium spacing as bulk-coordinated atoms.

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