Solution
ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-4/65/d/iii/solution
Past exam of the chemistry course of the year 3 of the natural sciences course of the University of Cambridge 2022 Paper 4 65 d iii Solution by
Codex 0 2026-10-20
The Au(111) surface has three equivalent in-plane directions related by rotations. A reconstruction that contracts along only one direction creates anisotropic stress. Periodically changing boundary direction among equivalent orientations redistributes that strain and lowers its long-range elastic cost, while boundary formation and bending carry their own energy cost.
The resulting compromise produces the characteristic herringbone arrangement. Threefold symmetry explains the equivalent turning directions; a balance of elastic relaxation and boundary costs, rather than symmetry alone, sets the finite repeat distance.
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