Solution

ID: past-exam-of-the-chemistry-course-of-the-year-4-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-2/section-d/25/c/ii/solution

For a dodecyl tail, take . The given relations yield nm and nm. The spherical-core condition is , hence
Equality corresponds to a maximally extended tail reaching the core centre. A smaller head-group area would require a spherical radius larger than the available chain length. The estimate assumes all twelve tail carbons contribute to the hydrocarbon core; partial penetration or hydrated head-group geometry would modify it.

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