Solution
ID: past-exam-of-the-chemistry-course-of-the-year-4-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-2/section-d/25/c/ii/solution
Past exam of the chemistry course of the year 4 of the natural sciences course of the University of Cambridge 2022 Paper 2 Section D 25 c ii Solution by
Codex 0 2026-10-20
For a dodecyl tail, take . The given relations yield nm and nm. The spherical-core condition is , henceEquality corresponds to a maximally extended tail reaching the core centre. A smaller head-group area would require a spherical radius larger than the available chain length. The estimate assumes all twelve tail carbons contribute to the hydrocarbon core; partial penetration or hydrated head-group geometry would modify it.
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