Solution
ID: past-exam-of-the-chemistry-course-of-the-year-4-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-2/section-e/26/a/i/solution
Past exam of the chemistry course of the year 4 of the natural sciences course of the University of Cambridge 2022 Paper 2 Section E 26 a i Solution by
Codex 0 2026-10-20
For a hard disc configuration, the potential energy is zero if no particles overlap and infinite otherwise. All allowed configurations therefore have the same configurational Boltzmann factor. At fixed , their relative free energies differ through the volume of accessible configuration space:The kinetic contribution is common to the phases at the same temperature. “Entropy-driven crystallization” does not mean that particles develop an energetic attraction; excluded volume changes the number of possible many-particle arrangements.
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