Solution

ID: past-exam-of-the-chemistry-course-of-the-year-4-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-2/section-e/26/a/i/solution

For a hard disc configuration, the potential energy is zero if no particles overlap and infinite otherwise. All allowed configurations therefore have the same configurational Boltzmann factor. At fixed , their relative free energies differ through the volume of accessible configuration space:
The kinetic contribution is common to the phases at the same temperature. “Entropy-driven crystallization” does not mean that particles develop an energetic attraction; excluded volume changes the number of possible many-particle arrangements.

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