 Solution

An $f$ shell has orbital quantum number $l=3$ and seven orbital states with $m_l=-3,-2,\dots ,3$. The first of Hund's rules maximizes total spin subject to the Pauli exclusion principle. Seven electrons occupy the seven orbitals singly with parallel spins, givingTheir orbital projections sum to zero, so the half-filled shell also has total orbital angular momentum $L=0$, total $J=7/2$, and Landé g-factor $g_J=2$. These further values identify the magnetic moment used below.