 Solution

At each reflection, the argument of the atomic scattering factor isSubstitution into the given atomic scattering factor approximation givesThus the structure factors are $S_{110}=36.2620$ and $S_{111}=113.7340$. The powder diffraction multiplicity is $m_{110}=12$: choose which Miller index is zero in three ways and the signs of the other two in four ways. For $\{111\}$, the eight sign choices give $m_{111}=8$. With the specified instrumental and angular factors omitted, the integrated powder diffraction wave intensity is proportional to $m_{hkl}|S_{hkl}{|}^2$, soIt would be incorrect to use the same atomic scattering factors at the two different scattering vectors, or to omit the powder diffraction multiplicity.