Solution

ID: past-exam-of-the-condensed-matter-physics-major-option-course-of-the-university-of-oxford/2016/1/c/solution

Write , where the four-site orbit has structure factor
A cyclic permutation of fixes the first term and permutes the remaining three. Thus . Substituting exchanges the first and second exponentials and the third and fourth, with the common coefficient :
The two forms of this phase, and , agree for integer indices. Multiplication by a unit-modulus phase preserves intensity, irrespective of whether is real or complex. Since the phase is independent of and atomic species, it also multiplies the total structure factor of the crystal.

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