Solution

ID: past-exam-of-the-condensed-matter-physics-major-option-course-of-the-university-of-oxford/2019/4/c/i/solution

The term is the leading electronic energy gain from splitting the initially degenerate orbitals and occupying the lower levels. Its negative sign expresses the lowering of the occupied-electron energy for the chosen elongation branch of the Jahn-Teller effect. The positive coefficient is a linear electron-lattice coupling in this reduced model.
The term is the harmonic elastic cost of moving the ligands away from the undistorted reference structure. Mechanical stability requires . The competition between linear gain and quadratic cost produces a finite equilibrium distortion rather than indefinite elongation.

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