Solution
ID: past-exam-of-the-materials-science-course-of-the-university-of-cambridge/2015/paper-1/6/c/solution
Past exam of the materials science course of the University of Cambridge 2015 Paper 1 6 c Solution by
Codex 0 2026-10-20
Diamond can be metastable: its Gibbs free energy is higher than graphite's under ambient conditions, but transformation is kinetically inhibited. Conversion requires substantial rearrangement of the strong carbon-bond network and the formation and growth of a new thermodynamic phase, with an activation and nucleation barrier.
At room temperature the rate can be extremely small even though the free-energy change favors graphite. Thermodynamic stability specifies the preferred equilibrium state, not the time needed to reach it. Persistence of diamond therefore does not contradict graphite's ambient equilibrium stability.
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