Solution

ID: past-exam-of-the-mathematics-course-of-the-university-of-cambridge/2001/iii/paper-72/2/b/solution

A further derivative gives the magnetic susceptibility within a selected pure thermodynamic phase:
Assuming a finite nonzero zero-field amplitude on the branch considered, comparison with gives
Together with part (a), this proves the Rushbrooke scaling relation and the Widom scaling relation . Below the transition, use the one-sided response of an ordered phase; differentiating through the cusp of the equilibrium free energy at would include phase switching rather than this critical response.

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