Solution

ID: past-exam-of-the-mathematics-course-of-the-university-of-cambridge/2008/iii/paper-50/1/c/solution

A first-order phase transition exchanges distinct global minima of the Landau free energy; the order parameter jumps and a thermal crossing generically has latent heat. A continuous phase transition has minima merging continuously and a diverging correlation length. A local loss of stability at a spinodal point is not the equilibrium coexistence condition.
For the sextic even Landau potential, write . At a nonzero zero-field stationary point, . To coexist with , also require . Eliminate to obtain and , which requires . On this locus
proving that all three equal minima are globally stable. Their curvatures are at zero and at the nonzero minima, so the correlation length is finite when is fixed. For , by contrast, the nonzero minimum approaches zero as , giving the ordinary continuous transition. At fixed and , crossing exchanges the two ordered minima discontinuously even though the zero-field thermal transition at is continuous.

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