Solution

ID: past-exam-of-the-mathematics-course-of-the-university-of-cambridge/2009/iii/paper-43/1/d/solution

Set in the even sextic Landau free energy. For , near the nonzero stationary branch satisfies for . The minimum value is below the transition and zero above. The order parameter is continuous, and if crosses zero linearly with temperature, the first temperature derivative of the minimized free-energy density is continuous too. There is no latent heat; a second derivative has a finite jump at this level.
For , solve the two conditions and with . Setting gives and . Eliminating gives
Both the disordered and ordered minima have positive curvature there, but their values coincide. Crossing this phase coexistence boundary changes the global minimum discontinuously. The order parameter jumps; for at fixed , jumps as well, generically yielding a nonzero latent heat. Local extrema can persist past coexistence as metastable states, which explains hysteresis in a dynamically delayed transition. The spinodal points, where local curvature vanishes, do not locate the equilibrium transition.

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