 Solution

Nielsen's pure-state conversion theorem gives the exact deterministic LOCC criterion. Let the Schmidt decompositions be $|\psi ⟩={\sum }_j\sqrt{{\lambda }_j}|a_j{b}_j⟩$ and $|\varphi ⟩={\sum }_j\sqrt{{\mu }_j}|a_j^{\prime }{b}_j^{\prime }⟩$. The vectors $\lambda ,\mu$ consist of squared Schmidt coefficients, equivalently the eigenvalues of either reduced density operator. Order each in decreasing order and pad with zeros to a common length $d$.

Then deterministic conversion is possible if and only ifThis is majorization, with the input vector majorized by the output vector. The direction matters: a maximally entangled state has a uniform vector, which is majorized by a product state's vector $(1,0,\dots )$, so entanglement can be discarded by LOCC. The criterion is for certain exact conversion, without catalysts or postselection on a successful branch.