 Solution

Choose an injection $j:A\to \mathbb{N}$. For each $b\in B$, its fiber under the surjection $f$ is nonempty, so defineTwo distinct fibers cannot contain the same label $j(a)$, because $j$ is an injection and $f(a)$ has a single value. Thus $h:B\to \mathbb{N}$ is an injection, proving that $B$ is a countable set. Taking the least label avoids any need for a separate choice of one element from each fiber. If $A$ is empty, surjectivity makes $B$ empty as well.

For the unheaded enumeration request, list pairs of positive natural numbers by their sum. An explicit Cantor pairing function isFor $d=m+n-2\ge 0$, the positive integers $n=1,\dots ,d+1$ give the consecutive labels $d(d+1)/2+1,\dots ,(d+1)(d+2)/2$. These blocks are disjoint, consecutive and cover $\mathbb{N}$. Consequently $\pi$ is a bijection from $\mathbb{N}\times \mathbb{N}$ to $\mathbb{N}$, so $\mathbb{N}\times \mathbb{N}$ is countable.