 Solution

A nonzero finite-dimensional quiver representation is a brick module when ${\mathrm{End}}_Q(X)=k{1}_X$. If $X=U\oplus V$ with both summands nonzero, projection onto $U$ is an idempotent endomorphism different from zero and the identity. That is impossible in $k{1}_X$. Hence every brick is indecomposable.

For the requested converse counterexample, take the dual-number algebra $A=k[\epsilon ]/({\epsilon }^2)$ and its left regular module $A$. The algebra is local with maximal ideal $(\epsilon )$, and it is not simple because this is a nonzero proper ideal. The module is indecomposable: its endomorphism ring is $A^{\mathrm{op}}\cong A$, which has no nontrivial idempotents. But this ring has dimension two over $k$, so the regular module is not a brick. Thus indecomposable need not mean brick without the positive-definiteness hypothesis used below.