 Solution

If $\theta$ is measure-preserving, equality holds on every measurable set and hence on the specified $\pi$-system. Conversely, let $\mathcal{D}=\{A\in \mathcal{E}:{\mu }_{\theta }(A)=\mu (A)\}$. Both finite measures have equal total mass. Therefore $E\in \mathcal{D}$, complements of members remain in $\mathcal{D}$ by subtracting from the finite total mass, and disjoint countable unions remain in $\mathcal{D}$ by countable additivity. Thus $\mathcal{D}$ is a Dynkin system.

It contains the generating pi-system $\mathcal{A}$, so Dynkin lemma gives $\mathcal{E}=\sigma (\mathcal{A})\subseteq \mathcal{D}$. ConsequentlyThis is exactly the measure-preserving property.