Solution

ID: past-exam-of-the-mathematics-course-of-the-university-of-cambridge/2019/ii/paper-4/34d/i/solution

Landau theory represents the appropriate thermodynamic potential as an analytic function of a small order parameter, retaining every low-order term allowed by the system's symmetry. At fixed control parameters, the equilibrium phase is the global minimum of the Landau free energy; local minima describe metastable phases. A continuous phase transition occurs when a minimum changes continuously and loses stability, whereas a first-order phase transition occurs when distinct minima exchange global stability.
For
the stationary points satisfy
If , is the unique minimum. If , is a maximum and the two degenerate minima are
Thus the reflection symmetry is spontaneously broken below , and

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