 Solution

Suppose $u_1,u_2$ are solutions and put $w=u_1-u_2$. Then $\Delta w=0$ and $w$ satisfies the homogeneous Robin boundary conditionFor $0<\lambda <1$, Green's first identity givesThe left side is nonnegative, so both sides vanish and $w=0$. For $\lambda =0$, the Dirichlet boundary condition $w=0$ on $S$ and the same identity again imply $w=0$. The solution is therefore unique for every $0\le \lambda <1$.

For a regular spherically symmetric solution, the Laplacian equation isRegularity at the origin gives $u^{\prime }=2r$, hence $u=r^2+C$. Applying the boundary condition at $r=b$ yieldsAt $\lambda =1$ the Neumann boundary condition would require $u^{\prime }(b)=2b=0$, which is impossible for $b>0$. Equivalently, its compatibility condition would require ${\int }_{V}6dV=0$.