Solution
ID: past-exam-of-the-mphil-in-micro-and-nanotechnology-enterprise-course-of-the-university-of-cambridge/2019/paper-2/section-a-i/13/i/solution
Past exam of the MPhil in micro- and nanotechnology enterprise course of the University of Cambridge 2019 Paper 2 Section A(i) 13 i Solution by
Codex 0 2026-10-20
A faceted, approximately equiaxed crystal is indicated. A truncated octahedron bounded by low-energy and facets is a plausible three-dimensional shape for an fcc metal particle; the hexagonal section alone does not uniquely distinguish it from other faceted polyhedra.
The Wulff construction minimizes at fixed particle volume. Place a plane with normal a distance from a common centre and take the inner envelope. Low-surface-energy orientations survive as large facets. Annealing permits diffusion toward this equilibrium morphology, provided the time is sufficient. For a supported or strained alloy, substrate adhesion and elastic energy modify this simple free-particle construction.
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