Solution

ID: past-exam-of-the-mphil-in-micro-and-nanotechnology-enterprise-course-of-the-university-of-cambridge/2020/paper-2/section-a-iii/18/ii/solution

Advance the projected contact line by per unit transverse length without wetting the gaps. A fraction converts solid–vapor interface into solid–liquid interface, contributing . The remaining fraction creates liquid–vapor interface above trapped gas, costing . The outer droplet surface contributes . Thus
Substituting Young's equation gives
This is the ideal Cassie–Baxter state relation. Its is projected solid-contact fraction, not the roughness factor of Wenzel wetting. A suspended interface over the gaps is essential; invasion of the texture changes the area bookkeeping.

New to topics? Read the docs here!