Solution

ID: past-exam-of-the-mphil-in-micro-and-nanotechnology-enterprise-course-of-the-university-of-cambridge/2020/paper-2/section-b/19/iii/c/solution

Yes: carbon nanotubes can store lithium and form a porous, conducting anode network. Their external surfaces, defects and intertube spaces provide possible storage sites. Open ends and suitable defects may make internal surfaces accessible; a closed pristine tube should not be credited with its full internal area.
Axial conduction and an entangled mechanical scaffold can support either active storage or a composite electrode. Limitations include tube–tube contact resistance, low packing density, catalyst residues and large-area solid electrolyte interphase formation. Opening or functionalizing tubes may improve ion access while increasing defects and irreversible reactions. Compare reversible capacity, first-cycle efficiency, retention and full-cell lithium inventory under matched loading and voltage-window conditions. A high first-cycle capacity alone is insufficient evidence of a superior anode.

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