Solution

ID: past-exam-of-the-mphil-in-micro-and-nanotechnology-enterprise-course-of-the-university-of-cambridge/2021/paper-1/11/ii/c/solution

For the reaction there is one mole of transferred electrons per mole of reaction. Treating the supplied fresh-cell open-circuit voltage as the standard equilibrium cell potential gives
A fresh-cell voltage alone would not normally establish standard conditions or equilibrium. The result above is the formal standard-free-energy estimate under the interpretation required to use the given datum; a metastable open-circuit voltage should not be mistaken for an independently measured standard thermodynamic potential.

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