Solution
ID: past-exam-of-the-mphil-in-micro-and-nanotechnology-enterprise-course-of-the-university-of-cambridge/2022/paper-2/section-a-i/14/i/b/solution
Past exam of the MPhil in micro- and nanotechnology enterprise course of the University of Cambridge 2022 Paper 2 Section A(i) 14 i b Solution by
Codex 0 2026-10-20
Potential advantages are reproducible thickness increments, large-area uniformity, conformal access to features and compatibility with moderate-temperature integration. Saturated exposure can make coverage less sensitive to small precursor-flux variations than an unsaturated deposition rate. The cycle count provides a useful process variable for matching an optical or electrical thickness target.
For a monolayer device, control of nucleation and coalescence is especially valuable, because excessive second-layer growth and uncovered patches both change the optical response. The advantages are conditional: a reliable ALD window and suitable precursor chemistry are required, and conformality does not imply a single-crystal film. Long exposure and purge steps reduce throughput, residual ligands or impurities can remain, and post-growth crystallization may require temperatures that the integrated device cannot tolerate.
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