 Solution

Let $\mathbf{n}$ point from medium 1 to medium 2. Integrate $\nabla \cdot \mathbf{D}={\rho }_f$ over a thin Gaussian pillbox crossing the interface. As its thickness tends to zero, the side contribution vanishes and any free surface charge density ${\sigma }_f$ givesApply $\oint \mathbf{E}\cdot d\mathbf{\ell }=0$ to a thin rectangular loop spanning the same interface. Its short sides vanish in the limit, so the tangential electric field is continuous:For a clean dielectric interface with no free surface charge density, these electrostatic interface boundary conditions reduce to $D_{1n}=D_{2n}$ and $E_{1t}=E_{2t}$. In particular ${ϵ}_1{E}_{1n}={ϵ}_2{E}_{2n}$; the normal electric field itself need not be continuous. Bound polarization charge is already incorporated into $\mathbf{D}$.