 Solution

No countable subset works. For any countable set $A\subseteq \mathbb{R}$, choose $b_n\in (n,n+1/2)\setminus A$: each nonempty interval is uncountable. The sequence tends to infinity, so every tailis closed in $\mathbb{R}$ and disjoint from $A$. By part (i), $p(\mathbb{R}\setminus K_n)$ is open in $X_A$. These sets increase and cover $X_A$, since no point belongs to every tail. But any finite selection is contained in its largest member, which still misses every quotient point $p(b_k)$ in that member's remaining tail. The $b_k$ represent distinct singleton classes.

This is an open cover without a finite subcover, provingThe argument does not assume that $A$ is closed, bounded, or discrete. It is the noncompactness after collapsing a countable real subset obstruction.