 Photoemission momentum conversion

For emission angle $\theta$ measured from the surface normal, a free outgoing photoelectron has parallel wavevector $k_{\parallel }=\sqrt{2m_e{E}_{\mathrm{kin}}}\sin \theta /\hslash$. Translation symmetry parallel to a clean periodic surface conserves this component modulo a surface reciprocal lattice vector, after accounting for photon momentum when needed. With initial binding energy $E_B$ below the Fermi level, its kinetic energy immediately outside the sample is $E_{\mathrm{kin}}=h\nu -{\varphi }_s-E_B$, where ${\varphi }_s$ is the sample work function. This sample-vacuum energy is distinct from the analyzer-referenced energy when contact potentials are present. Perpendicular crystal momentum generally needs a final-state model, whereas a strictly two-dimensional band has no perpendicular dispersion to reconstruct.