 Picard group of the projective line

For any field $k$, degree identifies the Picard group of the projective line with $\mathbb{Z}$, generated by $\mathcal{O}(1)$. A closed point on the affine chart is cut out by an irreducible polynomial $f(t)$, whose divisor is that point minus $\mathrm{deg}(f)$ times infinity. Hence every divisor is linearly equivalent to its degree times infinity. Principal divisors have degree zero, so the degree map is injective as well as surjective. Thus a line bundle of degree $d$ is $\mathcal{O}(d)$.