 Relative-entropy barycenter of a quantum ensemble

The ensemble average $\overline{\omega }$ uniquely minimizes ${\sum }_j{p}_{j}D({\omega }_j\Vert \rho )$ over density operators $\rho$. Donald's identity separates this objective into a constant plus $D(\overline{\omega }\Vert \rho )$, and nonnegativity of quantum relative entropy proves the claim. The minimum is the Holevo quantity $S(\overline{\omega })-{\sum }_j{p}_{j}S({\omega }_j)$, equivalently the quantum mutual information of the associated classical-quantum state.