Singlet-triplet exchange splitting in helium

ID: singlet-triplet-exchange-splitting-in-helium

For fixed orthonormal orbitals , symmetrizing or antisymmetrizing gives electron-repulsion expectations and . Antisymmetry of the complete electronic state therefore places the singlet above the triplet by , with the positive Coulomb exchange integral. Orbital relaxation and further correlation refine this comparison. Exchange splitting here is a consequence of Fermi statistics and the electrostatic interaction, not a separate classical spin-spin force.

New to topics? Read the docs here!