Spin-flip scattering is a collision or scattering event that changes a particle's spin projection along a specified quantization axis. For electrons, coupling to another magnetic moment or coupling of motion to spin through spin-orbit coupling can transfer angular momentum between the electron spin and other degrees of freedom.
Repeated events can relax a nonequilibrium spin polarization, making spin-flip scattering one mechanism of spin relaxation. The axis and state basis must be stated: in a spin-orbit-coupled material, the propagating energy eigenstates need not be pure up or down states along one fixed axis. Conversely, decay of transverse coherence need not imply flips; different precession phases can cancel the ensemble's transverse signal while individual spin populations remain unchanged.
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