Spin-orbit splitting of the first excited two-electron oscillator level
ID: spin-orbit-splitting-of-the-first-excited-two-electron-oscillator-level
For the interaction built from the total two-electron spin and orbital angular momentum, set . The spin-dot-product eigenvalue identity then gives the shift in the title. In the first excited two-electron oscillator manifold, the singlet has and zero shift with multiplicity three. The triplet has , with shifts and multiplicities .
The multiplicities sum to twelve, and their weighted shift sums to zero. The specified interaction preserves both and ; it is distinct from summing separate single-electron spin-orbit interactions. Its shifts are exact within this model's invariant oscillator manifold, with weak coupling ensuring the original level ordering remains useful.
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