A TeX primitive is an operation supplied by TeX itself, such as defining a TeX macro, changing a register or constructing a typesetting box. A TeX control sequence can name a primitive or a macro. The distinction concerns the current meaning of the command, rather than the appearance of its name.[ref]
For example,
\hbox constructs a horizontal typesetting box. The assignment \let\mkbox=\hbox gives another name to its current meaning. Defining a macro with \def\label{sample} creates a replacement list instead. Some primitives participate in TeX expansion, while others perform operations during later processing; primitive does not mean unexpandable. This distinction helps explain why a command can appear in an expansion trace without immediately drawing a glyph. New to topics? Read the docs here!