 The Electrical Double Layer and the Theory of Electrocapillarity by David C. Grahame

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The Electrical Double Layer and the Theory of Electrocapillarity by David C. Grahame by

Codex  0 2026-10-20

Chemical Reviews 41(3), 441–501. Publisher: doi.org/10.1021/cr60130a002

Electrochemical Society primary-paper archive: knowledge.electrochem.org/estir/hist/hist-66-Grahame.pdf

Section VI, printed pp. 470–474, derives the diffuse-layer theory from Poisson and Boltzmann equations. Equations (43)–(48), printed p. 474, distinguish integrated charge, integral capacitance and differential capacitance. The archived PDF includes two preliminary pages before printed p. 441.

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