 Time-evolution operator

The time-evolution operator maps an initial quantum state to its state at a later time. For a time-independent Hamiltonian operator $H$, it is the unitary operator $U(t)=e^{-iHt/\hslash }$.

More generally, write $|\psi (t)⟩=U(t,t_0)|\psi (t_0)⟩$. The time-evolution operator obeysFor a constant self-adjoint Hamiltonian operator, $U(t,t_0)=\exp [-iH(t-t_0)/\hslash ]$. With zero as the initial time, this gives the group law $U(t+s)=U(t)U(s)$. Successive evolution is reversible; a measurement followed by conditioning on an outcome is a separate operation described by projective measurement.

For a time-dependent Hamiltonian operator, the defining equation is $i\hslash {\partial }_{t}U(t,t_0)=H(t)U(t,t_0)$. In finite dimension, a continuous Hermitian $H(t)$ still gives unitary time evolution, sinceThe solution is a time-ordered exponential, with later factors acting on the left. One may replace it by $\exp [-i{\int }_{t_0}^{t}H(s)ds/\hslash ]$ when $[H(s),H(s^{\prime })]=0$ at all times; independently changing pulse axes generally requires time ordering.^[ref]