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Ring cleavage of 1,3,5-Trioxane regenerates formaldehyde, whose strong carbon–oxygen pi bond stabilizes the monomer; in water much of it is further stabilized as its hydrate. acetal hydrolysis, particularly under acid catalysis, provides a route between the cyclic trimer and these monomeric forms.

The corresponding formal depolymerization of a siloxane would create ${\mathrm{R}}_2\mathrm{Si}=\mathrm{O}$ silanone units. Such ordinary small-substituent silanones have much less favourable pi bonding and are very reactive toward forming new Si–O–Si linkages. The connected siloxane is consequently preferred over a persistent aqueous solution of silanone monomers. This explains the intended contrast, but aqueous stability is conditional: acid or base can catalyse siloxane cleavage to silanols, and those silanols can condense again. Neither neutral-water inertness of every siloxane nor instantaneous neutral-water dissociation of every trioxane should be inferred.