Let be the magnitude of the incident particle's momentum. The relativistic energy-momentum relation gives
The stationary particle contributes rest energy and zero momentum. Conservation of four-momentum therefore gives equal photon energies . A photon has momentum magnitude , so if the two momentum vectors meet at angle ,
Substitution gives the angular relation for two-photon electron-positron annihilation, whose derivation depends only on the stipulated equal rest masses and equal photon energies:
All energies and the angle here are in the laboratory inertial frame.
For perpendicular photon trajectories, and hence . Since with Lorentz factor ,
For the small-speed limit, set and . The angle formula implies
Using therefore gives , so
At zero incident speed the momenta are equal and opposite, so , consistent with the expansion.
For , take the initial electron direction as the longitudinal axis and put . Incoming four-momentum conservation gives
The transverse components must cancel. In the noncollinear case the two transverse directions are opposite, and . Hence the ratio of longitudinal momentum times to energy is
Writing and , the last ratio is . It also equals whenever that denominator is nonzero. Since , the angular relation for two-photon electron-positron annihilation is
The positive root follows from . For noncollinear emission the positive momentum-to-energy ratio ensures , and ensures the stated denominator is positive.
The printed quotient needs a qualification for exactly collinear photons. The allowed configuration , has positive frequencies
which obey both conservation equations, but the printed left side is . Thus the quotient holds for noncollinear angles, or as its appropriate noncollinear limit. The undivided identity
remains true in the collinear case, where both sides vanish. The limit similarly requires care because the initial direction is then undefined and the photons are antiparallel.