The dual unit ball is weak-star metrizable if and only if is separable. For the converse direction, Banach-Alaoglu theorem makes a metrizable dual ball a compact metric space, and the evaluation map embeds isometrically into the separable space .
The continuous dual of a separable Banach space is separable in its weak-star topology, even when it is not norm separable. Banach-Alaoglu theorem and weak-star metrizability of the dual ball make the dual unit ball a separable compact metric space. The countable union of positive integer multiples of a countable dense subset of that ball is dense in the whole dual. This does not imply global weak-star metrizability.