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A concrete quantum quench experiment loaded a Bose-Einstein condensate of ${}^{87}\mathrm{Rb}$ chemical atoms from a magnetic field trap into an optical lattice: three orthogonal $838\mathrm{nm}$ laser standing waves, with approximately $125\mu \mathrm{m}$ beam waists. An $80\mathrm{ms}$ loading ramp preceded a $50\mu \mathrm{s}$ increase in lattice depth. This suppressed quantum tunnelling while retaining each well's vibrational ground state. The switch preserved atom-number populations rather than freezing every motional degree of freedom.^[ref]

After variable hold times, releasing the traps and taking photon absorption images after $16\mathrm{ms}$ of flight revealed disappearance and return of interference peaks. Background-subtracted peak counts supplied a coherent fraction. Varying final depth tested the predicted revival period $h/U$; varying initial depth tested the collapse's sensitivity to atom-number statistics. Peak broadening outside counting windows and spatial variation of $U$ limited later signals.^[ref]

Here $U$ is the on-site interaction energy. The approximate isolated-well Hamiltonian operator $H=U\hat{n}(\hat{n}-1)/2$, with number operator $\hat{n}$, gives different quantum phases to its number states, which later rephase. This is a many-level realization of the distinction between fixed populations and changing quantum phases.^[ref]

In a dilute gas, Bose-Einstein condensation makes a single one-particle state hold a substantial fraction of the bosons. This is a population effect: cooling reduces the number that the excited energy eigenstates can accommodate at thermal equilibrium. The surplus accumulates in a Bose-Einstein condensate. For an ideal gas the occupied mode is the trap ground state; interactions can deform that mode, as described by the Gross–Pitaevskii equation. Dilute does not mean classical: a small number density can still give overlapping thermal de Broglie wavelengths at sufficiently low temperature.

The appeal is that changing the trap changes a calculable Quantum Hamiltonian, while absorption imaging makes its population distribution visible. The Bose condensation in a three-dimensional harmonic trap below turns density of states into a prediction for a critical temperature and condensate fraction. These are separate questions from measuring matter-wave coherence or superfluidity.

Eric A. Cornell and Carl E. Wieman's joint lecture emphasizes the competition between useful elastic collisions, which restore thermal equilibrium during evaporative cooling, and collisions that remove or heat the trapped sample. A long trap lifetime alone is insufficient: reequilibration must keep up with evaporation.^[ref]

For a repulsive contact-interacting Bose-Einstein condensate, the classical Hamiltonian density generating evolution in a frame rotating at the chemical potential is $\mathcal{K}={\hslash }^2|\nabla \psi {|}^2/(2M)-\mu |\psi {|}^2+g|\psi {|}^4/2$. Its integral is the grand canonical ensemble generator $H-\mu N$, not the physical energy $H$ alone. For $g,\mu >0$ the uniform mean-field theory minima satisfy $|{\psi }_0{|}^2=\mu /g$, with a freely chosen constant phase. In the physical frame, the corresponding field has time factor $e^{-i\mu t/\hslash }$.

Let ${\psi }_0$ be the normalized stationary profile. Multiplying its stationary Gross–Pitaevskii equation by ${\psi }_0^{\ast }$, integrating and integrating the kinetic term by parts yieldsThis is not simply $H/N$: the quartic contribution is twice its contribution to that energy per particle. For an infinite periodic system one uses one cell and the corresponding cell particle number, or equivalently average densities.

At fixed lattice spacing, mean density $n$, coupling and temperature, the commonly used condensate compressibility in an optical lattice isIf compressibility means the thermodynamic volume response instead, the Gibbs-Duhem equation $dp=nd\mu$ at zero temperature gives ${\kappa }_T=[n^2(\partial \mu /\partial n{)}_s{]}^{-1}=\kappa /n$. Stating the convention removes this factor-of-density ambiguity; the lattice-depth derivative has the same sign at fixed $n$.

For the stable repulsive ground-band Bose-Einstein condensate, the intended trend is $\partial \kappa /\partial s<0$ for increasing nonzero lattice depth, with mean density held fixed. Deeper wells localize the field, enhancing the repulsive interaction response. To quantify this, in the weak-interaction band approximation write ${\psi }_0=\sqrt{n}{f}_s$, with the cell average of $|f_s{|}^2$ equal to one. Perturbation in $Un$ givesIn deep wells the localized orbital is approximately a normalized Gaussian of width $a_{\mathrm{ho}}=d/(\pi s^{1/4})$. Neglecting interwell overlap, $I\simeq d/(\sqrt{2\pi }{a}_{\mathrm{ho}})=\sqrt{\pi /2}{s}^{1/4}$, hence $\partial \kappa /\partial s\simeq -\kappa /(4s)<0$. This explicitly establishes the sign in that controlled regime; the repulsive ground-band calculation describes the broader trend.

The sign statement needs the repulsive, stable ground-band interpretation, not merely the literal assumption $U\ne 0$. It also need not be a strictly nonzero derivative at $s=0$: at weak interaction $f_s=1+(s/8)\cos (2\pi x/d)+O(s^2)$, with normalization corrected at second order, gives $I=1+s^2/32+O(s^3)$ and a zero initial slope. A leading density-dominated Thomas–Fermi approximation for a condensate with density positive everywhere gives $\mu =Un+s{E}_R/2$ and no depth dependence of this response at that approximation's order. These limits do not justify a strict universal sign for every unspecified interaction and parameter regime.

Below $T_c$ the fugacity is $z=1$ in the continuum ideal-gas approximation. The zero-energy condensate contributes no internal energy, so the same Bose integral with one additional factor of energy givesEliminate $B$ using $N=B\Gamma (9/2)\zeta (9/2)(k_B{T}_c{)}^{9/2}$ and $\Gamma (11/2)=(9/2)\Gamma (9/2)$:The excited fraction is $(T/T_c{)}^{9/2}$ and the remaining particles occupy the Bose-Einstein condensate. For fixed $B$, the condensed-state energy at fixed $T$ is independent of how many additional particles are placed in the zero-energy ground state.

A homogeneous static saddle minimizes $f(\rho )=-\mu \rho +g{\rho }^2/2$ for $\rho =|\psi {|}^2\ge 0$. With $g>0$ and $\mu >0$,The mean-field Bose-Einstein condensate has a macroscopic coherent occupation of the uniform mode. Its continuous particle-number phase symmetry is $\psi \mapsto e^{i\chi }\psi$, the circle group $U(1)$ generated by particle number. Choosing one phase breaks it, and the saddle manifold is a circle. For $\mu \le 0$, the constrained minimum is the vacuum ${\rho }_0=0$, so the condensed saddle requires the stated positive-density regime.

Spontaneous symmetry breaking is understood through a phase-selected thermodynamic description: an exact finite-volume number eigenstate has vanishing field expectation. The resulting Goldstone boson is a gapless phase/sound mode, while phase gradients carry the superfluid velocity $\mathbf{v}=\nabla \varphi /m$. This is the saddle-point conclusion requested, not a proof of true condensate order in every dimension or temperature. Long-wavelength phase fluctuations can invalidate the assumed order, as quantified below.

Write $G(r)=⟨{\psi }^{†}(0)\psi (\mathbf{r})⟩$, $r=|\mathbf{r}|$, and ${\ell }^2=\hslash /(m\omega )$. At zero temperature all $N$ particles occupy ${\varphi }_0(\mathbf{r})=(\ell \sqrt{\pi }{)}^{-1}{e}^{-r^2/(2{\ell }^2)}$. Expanding the bosonic annihilation operator in single-particle orbitals givesThis one-body density matrix is a Gaussian function of width $\ell$; it contains one wavefunction evaluated at $r$, so its exponent is half that of the spatial number density $N|{\varphi }_0(r){|}^2$. In particular,the total number density at the trap centre, including condensed and noncondensed particles.

At positive temperature, with occupations ${\overline{n}}_a$ of the trap energy eigenstates, the exact ideal-gas decomposition isFor $\hslash \omega \ll k_{B}T<k_B{T}_c$, the sketch has a broad Bose-Einstein condensate component on scale $\ell$ and a narrower thermal peak near the origin. On approaching $T_c$ the broad component loses its weight $N_0$, while the thermal part remains. Above $T_c$ there is no macroscopic broad Bose-Einstein condensate component; close to $T_c$, low energy levels can still give a shoulder, so a single narrow Gaussian function is only a high-temperature description. At $k_{B}T\lesssim \hslash \omega$ individual excited energy levels matter and the two-scale description need not apply.

For $T\gg T_c$ the Maxwell-Boltzmann distribution applies. The leading off-diagonal one-body density matrix isHere ${\sigma }_r$ is the Gaussian function width defined by $e^{-r^2/(2{\sigma }_r^2)}$, and ${\lambda }_T$ is the thermal de Broglie wavelength. The thermal cloud itself extends over the much larger spatial scale $\sqrt{k_{B}T/\kappa }$; this is a correlation width, not the cloud radius.

The Hartree product state underlying the Gross–Pitaevskii equation has the factorized one-body coherence of a Hartree condensate. Choosing its nodeless ground state orbital real givesIn particular, the Thomas–Fermi approximation for a condensate from part (d) predictsThe curve starts at $\mu /g$, decreases with zero slope at the origin, and reaches zero with an infinite slope at $R$. Restoring the kinetic energy in the full Gross–Pitaevskii equation rounds that edge and produces a nonzero tail. This corrects the Thomas–Fermi approximation for a condensate, but the resulting one-body density matrix still factorizes.

The additional missing physics is quantum depletion. Interactions scatter pairs of bosons into orbitals outside the Bose-Einstein condensate even at zero temperature. In terms of the true Bose-Einstein condensate orbital ${\phi }_0$ the exact one-body density matrix decomposes asThe single-orbital Hartree product state sets $N_0=N$ and omits ${\rho }_{\mathrm{ex}}$ altogether. In a weakly interacting Bose gas, Bogoliubov theory adds a comparatively short-range noncondensed contribution near the origin, together with reduced weight in the broad Bose-Einstein condensate component. The central value remains the total number density, not just the condensate density. Its numerical shift relative to the original Gross–Pitaevskii equation solution also depends on the interaction-induced redistribution of number density; it is not fixed by the condensate fraction alone.

In three dimensions an ideal Bose gas can saturate its excited-state population at chemical potential zero, with the remaining particles forming a Bose-Einstein condensate. The transition follows from the Bose-Einstein distribution integrated against its density of states; below the ideal-gas transition, $n_0/n=1-(T/T_c{)}^{3/2}$. Condensation alone does not supply the finite Landau critical velocity of an interacting superfluid: the ideal quadratic spectrum has ${\inf }_{p}E(p)/p=0$.

By contrast, a weak attractive interaction near a Fermi surface produces the Cooper instability and the BCS gap equation. Its logarithmic enhancement permits pairing at arbitrarily weak attraction in the ideal model. The low-temperature excitations have $E=\sqrt{{\xi }^2+{\Delta }^2}$, and in weak coupling $k_B{T}_c=(e^{{\gamma }_E}/\pi )\Delta (0)\simeq 0.567\Delta (0)$. This transition is controlled by pair formation when phase fluctuations are small; deeply bound pairs instead motivate a Bose-condensation description with their own density and effective mass.

For the given ellipsoidal dispersion, set $q_x=k_x$, $q_y=k_y$ and $q_z=k_z/\sqrt{\gamma }$. Then $\epsilon ={\hslash }^2{q}^2/(2m)$ while the integration measure is $d^{3}k=\sqrt{\gamma }{d}^{3}q$. Thus the anisotropic ideal-gas density of states per unit volume and per internal state isThe full continuum momentum range is assumed; this is an anisotropic three-dimensional gas, not yet a discrete stack of two-dimensional bands.

At the Bose transition, substitute $x=\epsilon /(k_{B}T)$:The integral is $\Gamma (3/2)\zeta (3/2)\simeq 2.315$. Solving for the Bose-Einstein condensation temperature for an anisotropic effective mass givesThe heavier $z$-direction effective mass increases the available excited-state count and lowers the condensation temperature at fixed number density.

For a balanced two-spin Fermi gas, let $n_F$ denote total fermion number density and take $N_s$ to be the single-spin density of states used in the conventional gap equation. Counting the filled ellipsoid givesIf a spin-summed density of states is used instead, the coupling convention in the supplied integral must change accordingly; inserting a factor two into only one side would change the exponent incorrectly.

For ${\epsilon }_c\ll {\epsilon }_F$, replace the density of states across the interaction window by $N_s({\epsilon }_F,\gamma )$. Writing ${\lambda }_0=|g|N_{s0}$, the zero-temperature integral becomesand thereforeThe second expression additionally requires ${\lambda }_0{\gamma }^{1/3}\ll 1$. The explicit density dependence is ${\lambda }_0=|g|m(3{\pi }^2{n}_F{)}^{1/3}/(2{\pi }^2{\hslash }^2)$. This mass-anisotropy enhancement of a weak-coupling BCS gap initially raises the pairing scale, while the ideal Bose condensation scale decreases as ${\gamma }^{-1/3}$.

Large anisotropy weakens transport and coherence in the heavy direction. The separation of pair formation and phase ordering then matters, so a large mean-field gap need not imply a large actual $T_c$. A qualitative sketch has $T_c$ initially rising with the pairing scale and eventually turning down when coherence is the smaller scale. If preformed fermion pairs behave as bosons, use $n_B=n_F/2$ and pair mass about $2m$; in this continuum model this gives $k_B{T}^{\mathrm{BEC}}\simeq 0.218{\epsilon }_{F0}{\gamma }^{-1/3}$.

The turnover cannot be located reliably by taking the weak-coupling formulas to $\gamma \to \infty$: ${\epsilon }_F$ falls, ${\lambda }_0{\gamma }^{1/3}$ grows, the narrow-window assumption fails and the pair chemical potential and mass require a self-consistent treatment. The smooth curve in the figure is explicitly an illustrative interpolation of two extrapolated scales, not such a calculation. If actual decoupled two-dimensional layers are approached, ordinary ideal-gas finite-temperature condensation is absent and interacting phase order requires a different analysis, including the Berezinskii–Kosterlitz–Thouless transition when appropriate.

The cuprates make the distinction between pairing and phase coherence relevant: they are layered and have anisotropic motion, but their strong correlations, lattice band structure and predominantly d-wave superconductivity are outside this attractive continuum $s$-wave model. Anisotropy by itself is therefore not an explanation or quantitative fit of cuprate transition temperatures.

Measure energies from the single-particle ground state, and assume the three-dimensional ideal Bose gas in the large-particle-number limit. The harmonic-trap chemical-potential pinning discussed here uses a chemical potential satisfying ${\mu }_{\mathrm{ch}}\le 0$. On cooling, it approaches zero; below the condensation temperature it remains at zero to leading thermodynamic order. Above that temperature it is negative. The detailed negative-chemical-potential branch shape is determined by the density of states; the figure uses the harmonic trap analysed below. The finite-size condensate chemical potential stays slightly below zero rather than being exactly pinned there.

A Bose-Einstein condensate has macroscopic occupation of a single quantum state. A dilute atomic gas needs low temperature and high phase-space density while remaining metastable against ordinary liquid or solid formation. Laser cooling followed by evaporative cooling of atoms in a weak trap can achieve the required regime. For the trapped ideal gas the quantitative threshold is derived below; a uniform ideal gas has $n{\lambda }_T^3=\zeta (3/2)$ at onset. An experimental signature is a narrow low-momentum component appearing within the broader thermal distribution after time-of-flight expansion, as observed in magnetically trapped rubidium-87.^[ref]

Spinless cubic-box wave-vector counting. Impose periodic boundary conditions on a cube of side $L$. The allowed vectors are $\mathbf{k}=(2\pi /L)(n_x,n_y,n_z)$ with integer components. Each state occupies $(2\pi /L{)}^3$ in wave-vector space. For a spinless particle, counting the spherical shell givesThere is no spin multiplicity. This is continuum shell counting; a finite box has discrete levels. Using $ϵ={\hslash }^2{k}^2/(2m)$ gives the free-particle density of states per unit energy and volume

Semiclassical density of states in a central potential. At position $\mathbf{r}$, the available kinetic energy is $ϵ-U(r)$. The local-density approximation integrates the preceding free-particle result over the classically allowed region:This form assumes the allowed radial region is the connected interval $0\le r\le r_{ϵ}$. A nonmonotonic potential would require integrating all allowed shells.

For the isotropic harmonic trap, $r_{ϵ}=\sqrt{2ϵ/(m{\omega }^2)}$. Substituting $r=r_{ϵ}\sin \vartheta$ givesConsequentlyThe exact oscillator ground energy is $3\hslash \omega /2$ above the potential minimum. The harmonic-trap energy-zero convention subtracts that constant, while the displayed density of states is the leading semiclassical continuum expression, neglecting the finite-level corrections produced by that shift. The discrete ground state must be counted separately.

Condensate population. Below the transition, use ${\mu }_{\mathrm{ch}}\simeq 0$ for the excited states. The saturation of harmonic-trap excited states follows from the supplied integral:where $\zeta$ is the Riemann zeta function and $\zeta (3)\simeq 1.202$. Setting $N_{\mathrm{ex}}(T_0)=N$ gives the harmonic-trap critical-temperature prefactor:Above $T_0$ there is no macroscopic ground-state fraction in this approximation. For completeness, above the transition the quantum gas fugacity $z=e^{{\mu }_{\mathrm{ch}}/(k_{B}T)}<1$ satisfies $N=(k_{B}T/\hslash \omega {)}^3{\mathrm{Li}}_3(z)$; the polylogarithm ${\mathrm{Li}}_3$ therefore defines the plotted negative branch. A finite trapped gas has rounded behaviour, weak interactions shift the threshold, and the continuum thermal population is inaccurate when $k_{B}T$ is comparable to or below $\hslash \omega$. The power law is intended for the large-$N$ condensed regime, not an exact discrete-spectrum formula at arbitrarily small temperature.^[ref]

Expand a repulsive Bose-Einstein condensate around the real uniform saddle ${\psi }_0=\sqrt{\mu /g}$ as $\psi ={\psi }_0+\chi$. After removing a constant and a temporal boundary term, the quadratic Lagrangian density is the displayed expression. Its equation $i\hslash \dot{\chi }=-{\hslash }^2{\nabla }^2\chi /(2M)+\mu (\chi +{\chi }^{\ast })$ mixes a fluctuation and its complex conjugate. Writing $\chi ={\chi }_1+i{\chi }_2$ gives canonically paired amplitude and phase fluctuations and one positive Bogoliubov quasiparticle dispersion branch, $\hslash \omega =\sqrt{{ϵ}_k({ϵ}_k+2\mu )}$ with ${ϵ}_k={\hslash }^2{k}^2/(2M)$. The phase direction is a Goldstone mode; its zero uniform restoring force does not produce a second independent positive-frequency amplitude branch in this first-order-in-time theory.