Past exam of the mathematics course of the University of Cambridge 2015 ii Paper 4 31A Solution Created 2026-09-24 Updated 2026-10-06
The reciprocal lattice is . With oriented primitive-cell volume , its basis is and the cyclic variants; thus .
The total potential is . Using the Fourier transform convention , translation gives , withThe given Born approximation therefore supplies the amplitude . A finite geometric series gives, when the denominators are nonzero,At reciprocal-lattice vectors each phase is one, so , the number of atoms. For large finite crystals these narrow peaks represent coherent Bragg scattering, with peak intensity proportional to the squared number of atoms; their finite width reflects the finite crystal size.
For the specified face-centered cubic lattice, andThe reciprocal lattice have coordinates with all even or all odd. The two shortest nonzero length families are for and for . Elastic scattering satisfies . The assumed incident magnitude exceeds , so both families are kinematically accessible, andThis is the angular prediction for suitable crystal orientations, or for a powder containing those orientations. A fixed single-crystal orientation must additionally satisfy the vector Elastic Bragg scattering condition ; the magnitude bound alone cannot guarantee both peaks for every incident direction.