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Use the index convention $[e_a,e_c]=C_a{}^b{}_c{e}_b$. For the left- and right-invariant coframes, the Maurer-Cartan equations areTheir dual invariant vector fields satisfyFor example, evaluating $d{\lambda }^b$ on two dual fields gives $-{\lambda }^b([L_a,L_c])$, since its invariant coefficient functions are constant. The opposite right-invariant bracket gives the other sign. The mixed bracket vanishes because left and right translations commute.

For a semisimple Lie algebra, the Killing form $B(X,Y)=\mathrm{Tr}(\mathrm{ad}X\mathrm{ad}Y)$ is nondegenerate. It is adjoint invariant: using $\mathrm{ad}[Z,X]=[\mathrm{ad}Z,\mathrm{ad}X]$ and cyclicity of trace givesGroup conjugation preserves the trace as well, so this is invariant under the full group adjoint action. Translation supplies a bi-invariant pseudo-Riemannian metric.

Lower the indicated structure index by $C_{abc}=B_{be}{C}_a{}^e{}_c$. ThenThis changes sign under exchange of $a,c$ by the bracket and under exchange of $a,b$ by invariance. Hence $C_{abc}=C_{[abc]}$.

Let $\eta (X,Y,Z)=B(X,[Y,Z])$ at the identity and extend it as a left-invariant differential form. Its value is adjoint invariant, so the extended form is also right-invariant. The three-form in the question is $-\eta$ with the index-lowering convention just specified, an irrelevant overall sign for these properties. To prove closedness rather than only invariance, apply the exterior derivative on four left-invariant fields. Its six bracket terms combine by invariance intoThe final equality is the Jacobi identity. Therefore the Cartan three-formis both bi-invariant and closed.