Cartan three-form (${\eta }_e(X,Y,Z)=B(X,[Y,Z])$)

An adjoint-invariant symmetric bilinear form $B$ on a Lie algebra makes the displayed tensor alternating. If $B$ is invariant under the full group Adjoint representation, its left-translated three-form is also right-invariant. On left-invariant fields, the exterior derivative is $d\eta (W,X,Y,Z)=-2B(W,[X,[Y,Z]]+[Y,[Z,X]]+[Z,[X,Y]])=0$ by the Jacobi identity. The Killing form supplies such a $B$ on every semisimple Lie group. An overall sign change in the lowered structure-constant convention negates the form but not its invariance or closedness.