Bain path 2026-10-24
A continuous tetragonal deformation connecting FCC and BCC geometries. In a simple uniaxial version, retain basal conventional edges while reducing the third edge to . The alternate vectors , and form a BCC conventional cube, of half the volume of the deformed face-centered tetragonal cell. The name refers to Edgar Bain. Real metallurgical transformations can also change the other edges; this geometric path alone does not specify the energetic or kinetic transformation mechanism.
After compression along , let the original conventional edges be with . This gives exactly the specified volume reduction. The compressed FCC points admit the alternative translation vectors
They are mutually perpendicular, have equal length , and form a right-handed cube. Besides its corners, the lattice has the point
which is the compressed image of an original FCC face centre. All compressed FCC sites are generated by the cube's integer translations and this body-centre coset. Therefore
The old compressed tetragonal conventional cell has volume and four sites; the new BCC cube has half that volume and two sites. This verifies the same physical site density rather than silently losing atoms during the change of cell. The continuous uniaxial deformation is the Bain path, named for Edgar Bain.
Figure 1.
The Bain path: a rotated conventional cell exposes BCC geometry
. Original geometric construction. The basal panel shows the old square and a new square generated by the two diagonal half-translations. The spatial panel uses new-cell coordinates, with corner sites and a body centre. The compressed vertical edge and both new basal edges all have length . Dots are lattice sites rather than hard-sphere atomic surfaces. Details.