Madelung constant 2026-10-18
The Madelung constant, named for Erwin Madelung, is a dimensionless geometrical factor in the electrostatic binding of an ionic crystal. For a neutral lattice of electric charges with nearest unlike-ion distance , Coulomb's law gives the potential energy per ion pair as . At a positive reference site, , with neighboring electric charges . Both attraction and repulsion enter this lattice sum; summing with a neutral-bulk prescription is essential. Short-range overlap repulsion and other contributions must be added before inferring a stable spacing or a thermodynamic lattice energy.