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An Earth analogue has an iron-silicate interior and a thin secondary nitrogen-dominated atmosphere with water and carbon dioxide. Contextual coexistence of oxygen or ozone with methane and surface-water indicators would be a target biosignature. Its small scale height and extreme reflected-light contrast put a true Sun-Earth analogue beyond routine current atmospheric work, but future large direct-imaging missions and the Extremely Large Telescope target nearby terrestrial planets.

A temperate M-dwarf rocky planet has a similar solid interior but may retain carbon-dioxide, nitrogen, or water atmospheres under synchronous rotation. Water, carbon dioxide, methane, and contextual oxygen chemistry are observable targets. Its small host gives deeper transits, so the James Webb Space Telescope and large ground telescopes can test nearby systems, although stellar activity and atmospheric erosion complicate interpretation.

A Hycean planet or water-rich sub-Neptune has a water-rich interior or ocean below a hydrogen-rich atmosphere. Methane, carbon dioxide, ammonia, water, and proposed sulfur-bearing biosignatures must be interpreted against abiotic photochemistry. Its large radius and hydrogen scale height make transmission spectroscopy comparatively favorable for JWST and future Ariel space telescope surveys, but whether a clement ocean exists beneath the atmosphere remains model-dependent.

The Hubble Space Telescope uses ultraviolet through near-infrared transit and eclipse spectroscopy. It established detections of alkali metals, water, aerosols, and escaping hydrogen but has a small aperture and restricted continuous infrared coverage. High-resolution ground facilities such as the Very Large Telescope separate Doppler-shifted planetary lines from telluric and stellar spectra and directly image young giants; the atmosphere and thermal background limit broad-band precision. The James Webb Space Telescope uses NIRISS, NIRSpec, NIRCam, and MIRI for roughly visible-to-mid-infrared transit, eclipse, phase-curve, and direct-imaging spectroscopy. It has measured broad molecular inventories, including the clear carbon-dioxide feature and photochemical sulfur dioxide in WASP-39 b.

JWST improves on earlier facilities through its 6.5-metre collecting area, cold space environment, stable time-series spectroscopy, and broad infrared wavelength coverage spanning several bands of water, carbon dioxide, methane, carbon monoxide, ammonia, and sulfur compounds. The Ariel space telescope is designed for a uniform atmospheric census of about one thousand planets, while the Extremely Large Telescope will add spatial resolution and high-dispersion spectroscopy for nearby giant and terrestrial planets.

Three directions enabled or sharply advanced by JWST are chemically complete retrievals across multiple molecular bands rather than isolated detections; atmospheric tests of smaller and cooler sub-Neptunes and rocky planets; and measurements of photochemistry, clouds, heat redistribution, and vertical thermal structure through repeated transit, eclipse, and phase-resolved spectra.